IRIS publication 67959100
Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation
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TY - JOUR - Browne, Wesley R. and Passaniti, Paolo and Gandolfi, Maria Teresa and Ballardini, Roberto and Henry, William and Guckian, Adrian and O'Boyle, Noel and McGarvey, John J. and Vos, Johannes G. - 2007 - Inorganica Chimica Acta - Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation - Validated - () - 360 - 3 - 1183 - 1190 - The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x=0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved. - 10.1016/j.ica.2006.08.049 DA - 2007/NaN ER -
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@article{V67959100, = {Browne, Wesley R. and Passaniti, Paolo and Gandolfi, Maria Teresa and Ballardini, Roberto and Henry, William and Guckian, Adrian and O'Boyle, Noel and McGarvey, John J. and Vos, Johannes G.}, = {2007}, = {Inorganica Chimica Acta}, = {Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation}, = {Validated}, = {()}, = {360}, = {3}, pages = {1183--1190}, = {{The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x=0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved.}}, = {10.1016/j.ica.2006.08.049}, source = {IRIS} }
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AUTHORS | Browne, Wesley R. and Passaniti, Paolo and Gandolfi, Maria Teresa and Ballardini, Roberto and Henry, William and Guckian, Adrian and O'Boyle, Noel and McGarvey, John J. and Vos, Johannes G. | ||
YEAR | 2007 | ||
MONTH | |||
JOURNAL_CODE | Inorganica Chimica Acta | ||
TITLE | Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
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VOLUME | 360 | ||
ISSUE | 3 | ||
START_PAGE | 1183 | ||
END_PAGE | 1190 | ||
ABSTRACT | The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x=0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved. | ||
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DOI_LINK | 10.1016/j.ica.2006.08.049 | ||
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