TY  - JOUR
  - Gherman, T.,Venables, D. S.,Vaughan, S.,Orphal, J.,Ruth*, A. A.
  - 2008
  - February
  - Environmental Science ; Technology
  - Incoherent broadband cavity-enhanced absorption spectroscopy in the near-ultraviolet: Application to HONO and NO2
  - Validated
  - Altmetric: 1 ()
  - 42
  - 3
  - 890
  - 895
  - The first application of incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) in the near-ultraviolet for the simultaneous detection of two key atmospheric trace species, HONO and NO2, is reported. For both compounds the absorption is measured between 360 and 380 nm with a compact cavity-enhanced spectrometer employing a high power light-emitting diode. Detection limits of similar to 4 ppbv for HONO and similar to 14 ppbv for NO2 are reported for a static gas cell setup using a 20 s acquisition time. Based on an acquisition time of 10 min and an optical cavity length of 4.5 m detection limits of similar to 0.13 ppbv and similar to 0.38 ppbv were found for HONO and NO2 in a 4 m(3) atmospheric simulation chamber, demonstrating the usefulness of this approach for in situ monitoring of these important species in laboratory studies or field campaigns.
  - 0013-936X
  - http://hdl.handle.net/10468/796
  - 10.1021/es0716913
DA  - 2008/02
ER  - 

@article{V18609237,
   = {Gherman,  T. and Venables,  D. S. and Vaughan,  S. and Orphal,  J. and Ruth*,  A. A. },
   = {2008},
   = {February},
   = {Environmental Science ; Technology},
   = {Incoherent broadband cavity-enhanced absorption spectroscopy in the near-ultraviolet: Application to HONO and NO2},
   = {Validated},
   = {Altmetric: 1 ()},
   = {42},
   = {3},
  pages = {890--895},
   = {{The first application of incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) in the near-ultraviolet for the simultaneous detection of two key atmospheric trace species, HONO and NO2, is reported. For both compounds the absorption is measured between 360 and 380 nm with a compact cavity-enhanced spectrometer employing a high power light-emitting diode. Detection limits of similar to 4 ppbv for HONO and similar to 14 ppbv for NO2 are reported for a static gas cell setup using a 20 s acquisition time. Based on an acquisition time of 10 min and an optical cavity length of 4.5 m detection limits of similar to 0.13 ppbv and similar to 0.38 ppbv were found for HONO and NO2 in a 4 m(3) atmospheric simulation chamber, demonstrating the usefulness of this approach for in situ monitoring of these important species in laboratory studies or field campaigns.}},
  issn = {0013-936X},
   = {http://hdl.handle.net/10468/796},
   = {10.1021/es0716913},
  source = {IRIS}
}