TY  - JOUR
  - Venables, D. S.,Huang, K.,Schmuttenmaer, C. A.
  - 2001
  - September
  - Journal of Physical Chemistry B
  - Effect of reverse micelle size on the librational band of confined water and methanol
  - Validated
  - ()
  - 105
  - 38
  - 9132
  - 9138
  - We report measurement of the OH librational band in nanoscopic pools of water and methanol confined within reverse micelles. The librational band, which peaks near 670 cm(-1) in the bulk liquids, shifts to lower frequency as the reverse micelle size decreases. In addition, the shape of the band changes considerably as a function of decreasing size. The librational band at all compositions is well fit by a two-state model based on the relative fractions of bound and free water (or methanol) within the reverse micelles.
  - 1089-5647
  - 10.1021/jp0112065
DA  - 2001/09
ER  - 

@article{V18609297,
   = {Venables,  D. S. and Huang,  K. and Schmuttenmaer,  C. A. },
   = {2001},
   = {September},
   = {Journal of Physical Chemistry B},
   = {Effect of reverse micelle size on the librational band of confined water and methanol},
   = {Validated},
   = {()},
   = {105},
   = {38},
  pages = {9132--9138},
   = {{We report measurement of the OH librational band in nanoscopic pools of water and methanol confined within reverse micelles. The librational band, which peaks near 670 cm(-1) in the bulk liquids, shifts to lower frequency as the reverse micelle size decreases. In addition, the shape of the band changes considerably as a function of decreasing size. The librational band at all compositions is well fit by a two-state model based on the relative fractions of bound and free water (or methanol) within the reverse micelles.}},
  issn = {1089-5647},
   = {10.1021/jp0112065},
  source = {IRIS}
}