IRIS publication 16399747
Reflection-absorption IR spectrum of Chlorine Adatoms on the Silver(100) Surface
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TY - JOUR - 30.P. Hollins, A.A. Davis, D.A. Slater, M.A. Chesters, E.C. Hargreaves, P.M. Parlett, J.C. Wenger and M. Surman - 1996 - January - Journal of the Chemical Society, Faraday Transactions - Reflection-absorption IR spectrum of Chlorine Adatoms on the Silver(100) Surface - Published - () - 92 - 879 - 880 - The IR spectrum of chlorine adsorbed on the silver(100) surface has been recorded using the new IR beamline at the Daresbury Synchrotron Radiation Source: the performance of this facility in the far-IR region is shown to be comparable with the best that has been achieved in the mid-IR. An absorption band corresponding to the metal-chlorine stretching vibration was observed at 228 cm-1. Analysis of the intensity of this band indicates that the silver-chlorine bond exhibits significant ionic character, in agreement with recent cluster calculations. DA - 1996/01 ER -
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@article{V16399747, = {30.P. Hollins, A.A. Davis, D.A. Slater, M.A. Chesters, E.C. Hargreaves, P.M. Parlett, J.C. Wenger and M. Surman}, = {1996}, = {January}, = {Journal of the Chemical Society, Faraday Transactions}, = {Reflection-absorption IR spectrum of Chlorine Adatoms on the Silver(100) Surface}, = {Published}, = {()}, = {92}, pages = {879--880}, = {{The IR spectrum of chlorine adsorbed on the silver(100) surface has been recorded using the new IR beamline at the Daresbury Synchrotron Radiation Source: the performance of this facility in the far-IR region is shown to be comparable with the best that has been achieved in the mid-IR. An absorption band corresponding to the metal-chlorine stretching vibration was observed at 228 cm-1. Analysis of the intensity of this band indicates that the silver-chlorine bond exhibits significant ionic character, in agreement with recent cluster calculations.}}, source = {IRIS} }
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AUTHORS | 30.P. Hollins, A.A. Davis, D.A. Slater, M.A. Chesters, E.C. Hargreaves, P.M. Parlett, J.C. Wenger and M. Surman | ||
YEAR | 1996 | ||
MONTH | January | ||
JOURNAL_CODE | Journal of the Chemical Society, Faraday Transactions | ||
TITLE | Reflection-absorption IR spectrum of Chlorine Adatoms on the Silver(100) Surface | ||
STATUS | Published | ||
TIMES_CITED | () | ||
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VOLUME | 92 | ||
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START_PAGE | 879 | ||
END_PAGE | 880 | ||
ABSTRACT | The IR spectrum of chlorine adsorbed on the silver(100) surface has been recorded using the new IR beamline at the Daresbury Synchrotron Radiation Source: the performance of this facility in the far-IR region is shown to be comparable with the best that has been achieved in the mid-IR. An absorption band corresponding to the metal-chlorine stretching vibration was observed at 228 cm-1. Analysis of the intensity of this band indicates that the silver-chlorine bond exhibits significant ionic character, in agreement with recent cluster calculations. | ||
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