TY  - JOUR
  - Kourtchev, Ivan,Bejan, Iustinian,Sodeau, John R.,Wenger, John C.
  - 2009
  - June
  - Atmospheric Environment
  - Gas-phase reaction of (E)-[beta]-farnesene with ozone: Rate coefficient and carbonyl products
  - Validated
  - ()
  - 43
  - 20
  - 3182
  - 3190
  - The gas-phase ozonolysis of (E)-[beta]-farnesene was investigated in a 3.91 m3 atmospheric simulation chamber at 296 ± 2 K and relative humidity of around 0.1%. The relative rate method was used to determine the reaction rate coefficient of (4.01 ± 0.17) ÿ 10-16 cm3 molecule-1 s-1, where the indicated errors are two least-squares standard deviations and do not include uncertainties in the rate coefficients for the reference compounds ([gamma]-terpinene, cis-cyclooctene and 1,5-cyclooctadiene). Gas phase carbonyl products were collected using a denuder sampling technique and analyzed with GC/MS following derivatization with O-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA). The reaction products detected were acetone, 4-oxopentanal, methylglyoxal, 4-methylenehex-5-enal, 6-methylhept-5-en-2-one, and (E)-4-methyl-8-methylenedeca-4,9-dienal. A detailed mechanism for the gas-phase ozonolysis of (E)-[beta]-farnesene is proposed, which accounts for all of the products observed in this study. The results of this work indicate that the atmospheric reaction of (E)-[beta]-farnesene with ozone has a lifetime of around 1 h and is another possible source of the ubiquitous carbonyls, acetone, 4-oxopentanal and 6-methylhept-5-en-2-one in the atmosphere.
  - 1352-2310
  - http://www.sciencedirect.com/science/article/B6VH3-4W15KXR-F/2/73a69b5a6e11a06ed9d31de23ef87350
DA  - 2009/06
ER  - 

@article{V16705748,
   = {Kourtchev,  Ivan and Bejan,  Iustinian and Sodeau,  John R. and Wenger,  John C. },
   = {2009},
   = {June},
   = {Atmospheric Environment},
   = {Gas-phase reaction of (E)-[beta]-farnesene with ozone: Rate coefficient and carbonyl products},
   = {Validated},
   = {()},
   = {43},
   = {20},
  pages = {3182--3190},
   = {{The gas-phase ozonolysis of (E)-[beta]-farnesene was investigated in a 3.91 m3 atmospheric simulation chamber at 296 ± 2 K and relative humidity of around 0.1%. The relative rate method was used to determine the reaction rate coefficient of (4.01 ± 0.17) ÿ 10-16 cm3 molecule-1 s-1, where the indicated errors are two least-squares standard deviations and do not include uncertainties in the rate coefficients for the reference compounds ([gamma]-terpinene, cis-cyclooctene and 1,5-cyclooctadiene). Gas phase carbonyl products were collected using a denuder sampling technique and analyzed with GC/MS following derivatization with O-(2,3,4,5,6-pentafluorobenzyl) hydroxylamine (PFBHA). The reaction products detected were acetone, 4-oxopentanal, methylglyoxal, 4-methylenehex-5-enal, 6-methylhept-5-en-2-one, and (E)-4-methyl-8-methylenedeca-4,9-dienal. A detailed mechanism for the gas-phase ozonolysis of (E)-[beta]-farnesene is proposed, which accounts for all of the products observed in this study. The results of this work indicate that the atmospheric reaction of (E)-[beta]-farnesene with ozone has a lifetime of around 1 h and is another possible source of the ubiquitous carbonyls, acetone, 4-oxopentanal and 6-methylhept-5-en-2-one in the atmosphere.}},
  issn = {1352-2310},
   = {http://www.sciencedirect.com/science/article/B6VH3-4W15KXR-F/2/73a69b5a6e11a06ed9d31de23ef87350},
  source = {IRIS}
}