Migration of two antioxidants from packaging into a solid food and into Tenax (R)

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TY  - JOUR
  - Reinas, I,Oliveira, J,Pereira, J,Machado, F,Pocas, MF
  - 2012
  - January
  - Food Control
  - Migration of two antioxidants from packaging into a solid food and into Tenax (R)
  - Validated
  - ()
  - Migration Solid simulant Packaging Mathematical modelling Antioxidants Rice Tenax (R) PAPER REGULATIONS SIMULANTS MODELS
  - 28
  - 333
  - 337
  - The migration of chemicals from packaging materials into foods is an important issue in food safety and quality. European legislation sets specific migration limits which compliance must be assessed, surveyed and controlled by industry and authorities. Recently, the new Regulation UE 10/2011 included a new simulant - the Modified Polyphenylene Oxide (Tenax (R)) for solid dry foods. The objective of this work was to compare the migration kinetics of two antioxidants into Tenax (R) as compared to rice at 3 temperatures: 23,40 and 70 degrees C. The application of two different solutions of the 2nd Fick's law to describe and simulate the migration of the migrants to the present systems was studied. Diffusion coefficients ranged between 4.80E-13 and 2.84E-11 cm(2)/s for the migration into Tenax (R) and between 6.90E-18 and 4.33E-17 cm(2)/s for the migration into rice. The partition coefficients ranged between 6 and 29 for Tenax (R) and were over 1000 for rice. The activation energy for the migration into rice was half of that for Tenax (R). The models described relatively well the experimental data (epsilon < 12% and < 30% for rice and Tenax (R), respectively). Results indicate that the food simulant tends to overestimate migration values and thus can be safely used to assess materials compliance when materials are intended to contact with rice. However, results also indicate that Tenax (R) is a much more severe simulant in representing rice. (C) 2012 Elsevier Ltd. All rights reserved.
  - DOI 10.1016/j.foodcont.2012.05.023
DA  - 2012/01
ER  - 
@article{V190496168,
   = {Reinas,  I and Oliveira,  J and Pereira,  J and Machado,  F and Pocas,  MF },
   = {2012},
   = {January},
   = {Food Control},
   = {Migration of two antioxidants from packaging into a solid food and into Tenax (R)},
   = {Validated},
   = {()},
   = {Migration Solid simulant Packaging Mathematical modelling Antioxidants Rice Tenax (R) PAPER REGULATIONS SIMULANTS MODELS},
   = {28},
  pages = {333--337},
   = {{The migration of chemicals from packaging materials into foods is an important issue in food safety and quality. European legislation sets specific migration limits which compliance must be assessed, surveyed and controlled by industry and authorities. Recently, the new Regulation UE 10/2011 included a new simulant - the Modified Polyphenylene Oxide (Tenax (R)) for solid dry foods. The objective of this work was to compare the migration kinetics of two antioxidants into Tenax (R) as compared to rice at 3 temperatures: 23,40 and 70 degrees C. The application of two different solutions of the 2nd Fick's law to describe and simulate the migration of the migrants to the present systems was studied. Diffusion coefficients ranged between 4.80E-13 and 2.84E-11 cm(2)/s for the migration into Tenax (R) and between 6.90E-18 and 4.33E-17 cm(2)/s for the migration into rice. The partition coefficients ranged between 6 and 29 for Tenax (R) and were over 1000 for rice. The activation energy for the migration into rice was half of that for Tenax (R). The models described relatively well the experimental data (epsilon < 12% and < 30% for rice and Tenax (R), respectively). Results indicate that the food simulant tends to overestimate migration values and thus can be safely used to assess materials compliance when materials are intended to contact with rice. However, results also indicate that Tenax (R) is a much more severe simulant in representing rice. (C) 2012 Elsevier Ltd. All rights reserved.}},
   = {DOI 10.1016/j.foodcont.2012.05.023},
  source = {IRIS}
}
AUTHORSReinas, I,Oliveira, J,Pereira, J,Machado, F,Pocas, MF
YEAR2012
MONTHJanuary
JOURNAL_CODEFood Control
TITLEMigration of two antioxidants from packaging into a solid food and into Tenax (R)
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDMigration Solid simulant Packaging Mathematical modelling Antioxidants Rice Tenax (R) PAPER REGULATIONS SIMULANTS MODELS
VOLUME28
ISSUE
START_PAGE333
END_PAGE337
ABSTRACTThe migration of chemicals from packaging materials into foods is an important issue in food safety and quality. European legislation sets specific migration limits which compliance must be assessed, surveyed and controlled by industry and authorities. Recently, the new Regulation UE 10/2011 included a new simulant - the Modified Polyphenylene Oxide (Tenax (R)) for solid dry foods. The objective of this work was to compare the migration kinetics of two antioxidants into Tenax (R) as compared to rice at 3 temperatures: 23,40 and 70 degrees C. The application of two different solutions of the 2nd Fick's law to describe and simulate the migration of the migrants to the present systems was studied. Diffusion coefficients ranged between 4.80E-13 and 2.84E-11 cm(2)/s for the migration into Tenax (R) and between 6.90E-18 and 4.33E-17 cm(2)/s for the migration into rice. The partition coefficients ranged between 6 and 29 for Tenax (R) and were over 1000 for rice. The activation energy for the migration into rice was half of that for Tenax (R). The models described relatively well the experimental data (epsilon < 12% and < 30% for rice and Tenax (R), respectively). Results indicate that the food simulant tends to overestimate migration values and thus can be safely used to assess materials compliance when materials are intended to contact with rice. However, results also indicate that Tenax (R) is a much more severe simulant in representing rice. (C) 2012 Elsevier Ltd. All rights reserved.
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URL
DOI_LINKDOI 10.1016/j.foodcont.2012.05.023
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