IRIS publication 119669225
Synthesis of enantioenriched sulfoxides
RIS format for Endnote and similar
TY - JOUR - O'Mahony, Graham E. and Kelly, Padraig and Lawrence, Simon E. and Maguire, Anita R. - 2011 - Arkivoc - Synthesis of enantioenriched sulfoxides - Validated - () - 1 - 110 - This review discusses strategies for the asymmetric synthesis of sulfoxides, compounds with many applications in stereoselective synthesis and in some cases with pharmaceutical application. The review describes asymmetric oxidation, including metal catalyzed and nonmetal and biological oxidation processes, in addition to synthetic approaches via nucleophilic substitution of appropriately substituted precursors. Kinetic resolution in oxidation of sulfoxides to the analogous sulfones is also discussed; in certain instances, access to enantioenriched sulfoxides can be achieved via a combination of asymmetric sulfide oxidation and complementary kinetic resolution in sulfoxide oxidation. DA - 2011/NaN ER -
BIBTeX format for JabRef and similar
@article{V119669225, = {O'Mahony, Graham E. and Kelly, Padraig and Lawrence, Simon E. and Maguire, Anita R.}, = {2011}, = {Arkivoc}, = {Synthesis of enantioenriched sulfoxides}, = {Validated}, = {()}, pages = {1--110}, = {{This review discusses strategies for the asymmetric synthesis of sulfoxides, compounds with many applications in stereoselective synthesis and in some cases with pharmaceutical application. The review describes asymmetric oxidation, including metal catalyzed and nonmetal and biological oxidation processes, in addition to synthetic approaches via nucleophilic substitution of appropriately substituted precursors. Kinetic resolution in oxidation of sulfoxides to the analogous sulfones is also discussed; in certain instances, access to enantioenriched sulfoxides can be achieved via a combination of asymmetric sulfide oxidation and complementary kinetic resolution in sulfoxide oxidation.}}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | O'Mahony, Graham E. and Kelly, Padraig and Lawrence, Simon E. and Maguire, Anita R. | ||
YEAR | 2011 | ||
MONTH | |||
JOURNAL_CODE | Arkivoc | ||
TITLE | Synthesis of enantioenriched sulfoxides | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
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START_PAGE | 1 | ||
END_PAGE | 110 | ||
ABSTRACT | This review discusses strategies for the asymmetric synthesis of sulfoxides, compounds with many applications in stereoselective synthesis and in some cases with pharmaceutical application. The review describes asymmetric oxidation, including metal catalyzed and nonmetal and biological oxidation processes, in addition to synthetic approaches via nucleophilic substitution of appropriately substituted precursors. Kinetic resolution in oxidation of sulfoxides to the analogous sulfones is also discussed; in certain instances, access to enantioenriched sulfoxides can be achieved via a combination of asymmetric sulfide oxidation and complementary kinetic resolution in sulfoxide oxidation. | ||
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