Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones

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TY  - JOUR
  - Slattery, Catherine N. and Maguire, Anita R.
  - 2011
  - Organic ; Biomolecular Chemistry
  - Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones
  - Validated
  - ()
  - 9
  - 3
  - 667
  - 669
  - Asymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion.
DA  - 2011/NaN
ER  - 
@article{V119669226,
   = {Slattery, Catherine N. and Maguire, Anita R.},
   = {2011},
   = {Organic ; Biomolecular Chemistry},
   = {Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones},
   = {Validated},
   = {()},
   = {9},
   = {3},
  pages = {667--669},
   = {{Asymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion.}},
  source = {IRIS}
}
AUTHORSSlattery, Catherine N. and Maguire, Anita R.
YEAR2011
MONTH
JOURNAL_CODEOrganic ; Biomolecular Chemistry
TITLEAsymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME9
ISSUE3
START_PAGE667
END_PAGE669
ABSTRACTAsymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion.
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