IRIS publication 119669226
Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones
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TY - JOUR - Slattery, Catherine N. and Maguire, Anita R. - 2011 - Organic ; Biomolecular Chemistry - Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones - Validated - () - 9 - 3 - 667 - 669 - Asymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion. DA - 2011/NaN ER -
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@article{V119669226, = {Slattery, Catherine N. and Maguire, Anita R.}, = {2011}, = {Organic ; Biomolecular Chemistry}, = {Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones}, = {Validated}, = {()}, = {9}, = {3}, pages = {667--669}, = {{Asymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion.}}, source = {IRIS} }
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AUTHORS | Slattery, Catherine N. and Maguire, Anita R. | ||
YEAR | 2011 | ||
MONTH | |||
JOURNAL_CODE | Organic ; Biomolecular Chemistry | ||
TITLE | Asymmetric copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto sulfones | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | |||
VOLUME | 9 | ||
ISSUE | 3 | ||
START_PAGE | 667 | ||
END_PAGE | 669 | ||
ABSTRACT | Asymmetric copper-catalysed intramolecular C-H insertion reactions of a series of alpha-diazo-beta-keto sulfones are reported. Enantioselectivities of up to 82% ee were achieved in moderate to good yield. These results represent the highest level of enantiocontrol achieved to date for a copper-catalysed cyclopentanone synthesis via C-H insertion. | ||
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