Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)

Typeset version

 

TY  - 
  - Other
  - Maguire, AR,Kelleher, LL,Ferguson, G
  - 1996
  - December
  - Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)
  - Validated
  - 1
  - ()
  - Bakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES
  - Efficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained.
  - 147
  - 158
DA  - 1996/12
ER  - 
@misc{V160958794,
   = {Other},
   = {Maguire,  AR and Kelleher,  LL and Ferguson,  G },
   = {1996},
   = {December},
   = {Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)},
   = {Validated},
   = {1},
   = {()},
   = {Bakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES},
   = {{Efficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained.}},
  pages = {147--158},
  source = {IRIS}
}
OTHER_PUB_TYPEOther
AUTHORSMaguire, AR,Kelleher, LL,Ferguson, G
YEAR1996
MONTHDecember
TITLEEfficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)
RESEARCHER_ROLE
STATUSValidated
PEER_REVIEW1
TIMES_CITED()
SEARCH_KEYWORDBakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES
REFERENCE
ABSTRACTEfficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained.
PUBLISHER_LOCATION
PUBLISHER
EDITORS
ISBN_ISSN
EDITION
URL
START_PAGE147
END_PAGE158
DOI_LINK
FUNDING_BODY
GRANT_DETAILS