IRIS publication 160958794
Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)
RIS format for Endnote and similar
TY - - Other - Maguire, AR,Kelleher, LL,Ferguson, G - 1996 - December - Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996) - Validated - 1 - () - Bakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES - Efficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained. - 147 - 158 DA - 1996/12 ER -
BIBTeX format for JabRef and similar
@misc{V160958794, = {Other}, = {Maguire, AR and Kelleher, LL and Ferguson, G }, = {1996}, = {December}, = {Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996)}, = {Validated}, = {1}, = {()}, = {Bakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES}, = {{Efficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained.}}, pages = {147--158}, source = {IRIS} }
Data as stored in IRIS
OTHER_PUB_TYPE | Other | ||
AUTHORS | Maguire, AR,Kelleher, LL,Ferguson, G | ||
YEAR | 1996 | ||
MONTH | December | ||
TITLE | Efficient kinetic resolution of 2-benzenesulfonylcyclopentanone derivatives (vol 1, pg 115, 1996) | ||
RESEARCHER_ROLE | |||
STATUS | Validated | ||
PEER_REVIEW | 1 | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | Bakers' yeast reduction beta-keto sulfones chiral derivatives cyclopentane derivatives kinetic resolution DESS-MARTIN PERIODINANE BAKERS-YEAST REDUCTION KETO ESTER SULFONES CHEMISTRY OXIDATION CONFIGURATION SULFIDES LACTONES | ||
REFERENCE | |||
ABSTRACT | Efficient kinetic resolution of 2-benzenesulfonylcyclopentanones 1, bearing 3-alkyl, 3-aryl, or 3-benzyl substituents, has been achieved by bakers' yeast mediated reduction. With the unsubstituted 2-benzenesulfonylcyclopentanone la, efficient asymmetric reduction to form (1S,2R)-cis-2-benzenesulfonylcyclopentanol 2a is observed under the same conditions. Excellent enantioselectivities (up to > 95% ee) are obtained. | ||
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START_PAGE | 147 | ||
END_PAGE | 158 | ||
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