IRIS publication 206307675
Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides
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TY - JOUR - Collins, SG,O'Sullivan, OCM,Kelleher, PG,Maguire, AR - 2013 - January - Organic ; Biomolecular Chemistry - Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides - Validated - () - C-H INSERTION METAL CARBENE TRANSFORMATIONS NUCLEAR-MAGNETIC-RESONANCE ORGANIC-SYNTHESIS DIAZOCARBONYL COMPOUNDS SULPHONYL AZIDE S-OXIDES 1,4-OXATHIAN-2-ONES DIAZOSULFOXIDES CHEMISTRY - 11 - 1706 - 1725 - Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable alpha-diazo-beta-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic alpha-diazo-beta-oxo sulfoxides are too labile to isolate and characterize. - DOI 10.1039/c3ob27061k DA - 2013/01 ER -
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@article{V206307675, = {Collins, SG and O'Sullivan, OCM and Kelleher, PG and Maguire, AR }, = {2013}, = {January}, = {Organic ; Biomolecular Chemistry}, = {Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides}, = {Validated}, = {()}, = {C-H INSERTION METAL CARBENE TRANSFORMATIONS NUCLEAR-MAGNETIC-RESONANCE ORGANIC-SYNTHESIS DIAZOCARBONYL COMPOUNDS SULPHONYL AZIDE S-OXIDES 1,4-OXATHIAN-2-ONES DIAZOSULFOXIDES CHEMISTRY}, = {11}, pages = {1706--1725}, = {{Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable alpha-diazo-beta-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic alpha-diazo-beta-oxo sulfoxides are too labile to isolate and characterize.}}, = {DOI 10.1039/c3ob27061k}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Collins, SG,O'Sullivan, OCM,Kelleher, PG,Maguire, AR | ||
YEAR | 2013 | ||
MONTH | January | ||
JOURNAL_CODE | Organic ; Biomolecular Chemistry | ||
TITLE | Design and synthesis of stable alpha-diazo-beta-oxo sulfoxides | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | C-H INSERTION METAL CARBENE TRANSFORMATIONS NUCLEAR-MAGNETIC-RESONANCE ORGANIC-SYNTHESIS DIAZOCARBONYL COMPOUNDS SULPHONYL AZIDE S-OXIDES 1,4-OXATHIAN-2-ONES DIAZOSULFOXIDES CHEMISTRY | ||
VOLUME | 11 | ||
ISSUE | |||
START_PAGE | 1706 | ||
END_PAGE | 1725 | ||
ABSTRACT | Diazo transfer adjacent to a sulfoxide moiety to provide stable, isolable alpha-diazo-beta-oxo sulfoxides has been achieved. Use of monocyclic and bicyclic sulfoxide precursors is critical in enabling isolation of stable derivatives, through introduction of conformational constraint, while acyclic alpha-diazo-beta-oxo sulfoxides are too labile to isolate and characterize. | ||
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DOI_LINK | DOI 10.1039/c3ob27061k | ||
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