IRIS publication 243942709
Copper-catalysed enantioselective intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates
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TY - JOUR - Slattery, CN,Maguire, AR - 2013 - May - Tetrahedron Letters - Copper-catalysed enantioselective intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates - Validated - WOS: 15 () - Diazocarbonyl C-H insertion Copper catalysis Bis(oxazoline) NaBARF DIAZOCARBONYL COMPOUNDS CARBENOID REACTIONS DECOMPOSITION DIAZOSULFONES CARBOXYLATES SUBSTITUENT YLIDES BONDS - 54 - 2799 - 2801 - Copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates are described, with moderate-to-good levels of enantioselectivity achieved for reactions employing the borate additive sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaBARF). Notably, the first example of asymmetric induction reported to date for intramolecular C-H insertion of an alpha-diazo-beta-keto phosphonate is also described. (C) 2013 Elsevier Ltd. All rights reserved. - 10.1016/j.tetlet.2013.03.078 DA - 2013/05 ER -
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@article{V243942709, = {Slattery, CN and Maguire, AR }, = {2013}, = {May}, = {Tetrahedron Letters}, = {Copper-catalysed enantioselective intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates}, = {Validated}, = {WOS: 15 ()}, = {Diazocarbonyl C-H insertion Copper catalysis Bis(oxazoline) NaBARF DIAZOCARBONYL COMPOUNDS CARBENOID REACTIONS DECOMPOSITION DIAZOSULFONES CARBOXYLATES SUBSTITUENT YLIDES BONDS}, = {54}, pages = {2799--2801}, = {{Copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates are described, with moderate-to-good levels of enantioselectivity achieved for reactions employing the borate additive sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaBARF). Notably, the first example of asymmetric induction reported to date for intramolecular C-H insertion of an alpha-diazo-beta-keto phosphonate is also described. (C) 2013 Elsevier Ltd. All rights reserved.}}, = {10.1016/j.tetlet.2013.03.078}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Slattery, CN,Maguire, AR | ||
YEAR | 2013 | ||
MONTH | May | ||
JOURNAL_CODE | Tetrahedron Letters | ||
TITLE | Copper-catalysed enantioselective intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates | ||
STATUS | Validated | ||
TIMES_CITED | WOS: 15 () | ||
SEARCH_KEYWORD | Diazocarbonyl C-H insertion Copper catalysis Bis(oxazoline) NaBARF DIAZOCARBONYL COMPOUNDS CARBENOID REACTIONS DECOMPOSITION DIAZOSULFONES CARBOXYLATES SUBSTITUENT YLIDES BONDS | ||
VOLUME | 54 | ||
ISSUE | |||
START_PAGE | 2799 | ||
END_PAGE | 2801 | ||
ABSTRACT | Copper-catalysed intramolecular C-H insertion reactions of alpha-diazo-beta-keto esters and alpha-diazo-beta-keto phosphonates are described, with moderate-to-good levels of enantioselectivity achieved for reactions employing the borate additive sodium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate (NaBARF). Notably, the first example of asymmetric induction reported to date for intramolecular C-H insertion of an alpha-diazo-beta-keto phosphonate is also described. (C) 2013 Elsevier Ltd. All rights reserved. | ||
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DOI_LINK | 10.1016/j.tetlet.2013.03.078 | ||
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