Electronic effects of aryl-substituted bis(oxazoline) ligands on the outcome of asymmetric copper-catalysed C-H insertion and aromatic addition reactions

Typeset version

 

TY  - JOUR
  - Slattery, CN,O'Keeffe, S,Maguire, AR
  - 2013
  - October
  - Tetrahedron-Asymmetry
  - Electronic effects of aryl-substituted bis(oxazoline) ligands on the outcome of asymmetric copper-catalysed C-H insertion and aromatic addition reactions
  - Validated
  - WOS: 6 ()
  - ALPHA-DIAZOCARBONYL COMPOUNDS ENANTIOSELECTIVE SYNTHESIS COMPLEXES CYCLOPROPANATION DIAZOSULFONES DERIVATIVES MECHANISM
  - 24
  - 1265
  - 1275
  - The effect of the modification of bis(oxazoline) ligands on the outcome of copper-catalysed C-H insertion and aromatic addition reactions is described. In general, these reactions display minimum sensitivity in terms of enantiocontrol to variation of the electronic properties of the aryl moiety of the ligand however, some influence is observed for C-H insertions employing naphthyl-substituted bis(oxazolines) and for aromatic addition reactions of biphenyl diazo ketone substrates. The synthesis of the modified bis(oxazolines), which include four novel structures, is also described. (C) 2013 Elsevier Ltd. All rights reserved.
  - 10.1016/j.tetasy.2013.09.009
DA  - 2013/10
ER  - 
@article{V243943622,
   = {Slattery,  CN and O'Keeffe,  S and Maguire,  AR },
   = {2013},
   = {October},
   = {Tetrahedron-Asymmetry},
   = {Electronic effects of aryl-substituted bis(oxazoline) ligands on the outcome of asymmetric copper-catalysed C-H insertion and aromatic addition reactions},
   = {Validated},
   = {WOS: 6 ()},
   = {ALPHA-DIAZOCARBONYL COMPOUNDS ENANTIOSELECTIVE SYNTHESIS COMPLEXES CYCLOPROPANATION DIAZOSULFONES DERIVATIVES MECHANISM},
   = {24},
  pages = {1265--1275},
   = {{The effect of the modification of bis(oxazoline) ligands on the outcome of copper-catalysed C-H insertion and aromatic addition reactions is described. In general, these reactions display minimum sensitivity in terms of enantiocontrol to variation of the electronic properties of the aryl moiety of the ligand however, some influence is observed for C-H insertions employing naphthyl-substituted bis(oxazolines) and for aromatic addition reactions of biphenyl diazo ketone substrates. The synthesis of the modified bis(oxazolines), which include four novel structures, is also described. (C) 2013 Elsevier Ltd. All rights reserved.}},
   = {10.1016/j.tetasy.2013.09.009},
  source = {IRIS}
}
AUTHORSSlattery, CN,O'Keeffe, S,Maguire, AR
YEAR2013
MONTHOctober
JOURNAL_CODETetrahedron-Asymmetry
TITLEElectronic effects of aryl-substituted bis(oxazoline) ligands on the outcome of asymmetric copper-catalysed C-H insertion and aromatic addition reactions
STATUSValidated
TIMES_CITEDWOS: 6 ()
SEARCH_KEYWORDALPHA-DIAZOCARBONYL COMPOUNDS ENANTIOSELECTIVE SYNTHESIS COMPLEXES CYCLOPROPANATION DIAZOSULFONES DERIVATIVES MECHANISM
VOLUME24
ISSUE
START_PAGE1265
END_PAGE1275
ABSTRACTThe effect of the modification of bis(oxazoline) ligands on the outcome of copper-catalysed C-H insertion and aromatic addition reactions is described. In general, these reactions display minimum sensitivity in terms of enantiocontrol to variation of the electronic properties of the aryl moiety of the ligand however, some influence is observed for C-H insertions employing naphthyl-substituted bis(oxazolines) and for aromatic addition reactions of biphenyl diazo ketone substrates. The synthesis of the modified bis(oxazolines), which include four novel structures, is also described. (C) 2013 Elsevier Ltd. All rights reserved.
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URL
DOI_LINK10.1016/j.tetasy.2013.09.009
FUNDING_BODY
GRANT_DETAILS