Asymmetric oxidation of sulfides

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TY  - JOUR
  - O'Mahony, GE,Ford, A,Maguire, AR
  - 2012
  - June
  - Journal Of Sulfur Chemistry
  - Asymmetric oxidation of sulfides
  - Validated
  - ()
  - sulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN
  - 34
  - 301
  - 341
  - This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined.
  - 10.1080/17415993.2012.725247
DA  - 2012/06
ER  - 
@article{V243944759,
   = {O'Mahony,  GE and Ford,  A and Maguire,  AR },
   = {2012},
   = {June},
   = {Journal Of Sulfur Chemistry},
   = {Asymmetric oxidation of sulfides},
   = {Validated},
   = {()},
   = {sulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN},
   = {34},
  pages = {301--341},
   = {{This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined.}},
   = {10.1080/17415993.2012.725247},
  source = {IRIS}
}
AUTHORSO'Mahony, GE,Ford, A,Maguire, AR
YEAR2012
MONTHJune
JOURNAL_CODEJournal Of Sulfur Chemistry
TITLEAsymmetric oxidation of sulfides
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDsulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN
VOLUME34
ISSUE
START_PAGE301
END_PAGE341
ABSTRACTThis review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined.
PUBLISHER_LOCATION
ISBN_ISSN
EDITION
URL
DOI_LINK10.1080/17415993.2012.725247
FUNDING_BODY
GRANT_DETAILS