IRIS publication 243944759
Asymmetric oxidation of sulfides
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TY - JOUR - O'Mahony, GE,Ford, A,Maguire, AR - 2012 - June - Journal Of Sulfur Chemistry - Asymmetric oxidation of sulfides - Validated - () - sulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN - 34 - 301 - 341 - This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined. - 10.1080/17415993.2012.725247 DA - 2012/06 ER -
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@article{V243944759, = {O'Mahony, GE and Ford, A and Maguire, AR }, = {2012}, = {June}, = {Journal Of Sulfur Chemistry}, = {Asymmetric oxidation of sulfides}, = {Validated}, = {()}, = {sulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN}, = {34}, pages = {301--341}, = {{This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined.}}, = {10.1080/17415993.2012.725247}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | O'Mahony, GE,Ford, A,Maguire, AR | ||
YEAR | 2012 | ||
MONTH | June | ||
JOURNAL_CODE | Journal Of Sulfur Chemistry | ||
TITLE | Asymmetric oxidation of sulfides | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | sulfide oxidation sulfoxides asymmetric synthesis enantioselective synthesis metal-based catalysts ALKYL ARYL SULFIDES CHIRAL SCHIFF-BASES HELMINTHOSPORIUM SPECIES NRRL-4671 OPTICALLY-ACTIVE SULFOXIDES BENZYL METHYL SULFOXIDES AQUEOUS HYDROGEN-PEROXIDE TERT-BUTYL HYDROPEROXIDE TWIN CORONET PORPHYRINS MANDELIC-ACID COMPLEX BOVINE SERUM-ALBUMIN | ||
VOLUME | 34 | ||
ISSUE | |||
START_PAGE | 301 | ||
END_PAGE | 341 | ||
ABSTRACT | This review discusses synthesis of enantiopure sulfoxides through the asymmetric oxidation of prochiral sulfides. The use of metal complexes to promote asymmetric sulfoxidation is described in detail, with a particular emphasis on the synthesis of biologically active sulfoxides. The use of non-metal-based systems, such as oxaziridines, chiral hydroperoxides and peracids, as well as enzyme-catalyzed sulfoxidations is also examined. | ||
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ISBN_ISSN | |||
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URL | |||
DOI_LINK | 10.1080/17415993.2012.725247 | ||
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