IRIS publication 271354797
Baker's-Yeast-Mediated Reduction of Sulfur-Containing Compounds
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TY - JOUR - Deasy, RE,Maguire, AR - 2014 - June - European Journal of Organic Chemistry - Baker's-Yeast-Mediated Reduction of Sulfur-Containing Compounds - Validated - Scopus: 9 () - Synthetic methods Enzyme catalysis Biotransformations Reduction Enantioselectivity Chiral alcohols Sulfur EFFICIENT ASYMMETRIC OXIDATION BIOLOGICALLY-ACTIVE COMPOUNDS BIFUNCTIONAL CHIRAL SYNTHONS ACID-CATALYZED CYCLIZATION HIGH OPTICAL PURITY ENANTIOSELECTIVE SYNTHESIS MICROBIAL REDUCTION STEREOSELECTIVE-SYNTHESIS SACCHAROMYCES-CEREVISIAE KINETIC RESOLUTION - 2014 - 3737 - 3756 - Both the efficiency and the stereoselectivity in baker's-yeast-mediated reduction of ketones are strongly influenced by both the presence and the position of sulfur substituents, or indeed by the use of sulfur-containing additives. Interestingly the oxidation level of the sulfur substituent has a powerful impact on the outcome of the yeast reduction. It is apparent that use of the sulfone moiety as a substituent to influence the efficiency and stereoselectivity in ketone reduction is substantially more effective than use of the analogous sulfide and sulfoxide moieties. - 10.1002/ejoc.201301729 DA - 2014/06 ER -
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@article{V271354797, = {Deasy, RE and Maguire, AR }, = {2014}, = {June}, = {European Journal of Organic Chemistry}, = {Baker's-Yeast-Mediated Reduction of Sulfur-Containing Compounds}, = {Validated}, = {Scopus: 9 ()}, = {Synthetic methods Enzyme catalysis Biotransformations Reduction Enantioselectivity Chiral alcohols Sulfur EFFICIENT ASYMMETRIC OXIDATION BIOLOGICALLY-ACTIVE COMPOUNDS BIFUNCTIONAL CHIRAL SYNTHONS ACID-CATALYZED CYCLIZATION HIGH OPTICAL PURITY ENANTIOSELECTIVE SYNTHESIS MICROBIAL REDUCTION STEREOSELECTIVE-SYNTHESIS SACCHAROMYCES-CEREVISIAE KINETIC RESOLUTION}, = {2014}, pages = {3737--3756}, = {{Both the efficiency and the stereoselectivity in baker's-yeast-mediated reduction of ketones are strongly influenced by both the presence and the position of sulfur substituents, or indeed by the use of sulfur-containing additives. Interestingly the oxidation level of the sulfur substituent has a powerful impact on the outcome of the yeast reduction. It is apparent that use of the sulfone moiety as a substituent to influence the efficiency and stereoselectivity in ketone reduction is substantially more effective than use of the analogous sulfide and sulfoxide moieties.}}, = {10.1002/ejoc.201301729}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Deasy, RE,Maguire, AR | ||
YEAR | 2014 | ||
MONTH | June | ||
JOURNAL_CODE | European Journal of Organic Chemistry | ||
TITLE | Baker's-Yeast-Mediated Reduction of Sulfur-Containing Compounds | ||
STATUS | Validated | ||
TIMES_CITED | Scopus: 9 () | ||
SEARCH_KEYWORD | Synthetic methods Enzyme catalysis Biotransformations Reduction Enantioselectivity Chiral alcohols Sulfur EFFICIENT ASYMMETRIC OXIDATION BIOLOGICALLY-ACTIVE COMPOUNDS BIFUNCTIONAL CHIRAL SYNTHONS ACID-CATALYZED CYCLIZATION HIGH OPTICAL PURITY ENANTIOSELECTIVE SYNTHESIS MICROBIAL REDUCTION STEREOSELECTIVE-SYNTHESIS SACCHAROMYCES-CEREVISIAE KINETIC RESOLUTION | ||
VOLUME | 2014 | ||
ISSUE | |||
START_PAGE | 3737 | ||
END_PAGE | 3756 | ||
ABSTRACT | Both the efficiency and the stereoselectivity in baker's-yeast-mediated reduction of ketones are strongly influenced by both the presence and the position of sulfur substituents, or indeed by the use of sulfur-containing additives. Interestingly the oxidation level of the sulfur substituent has a powerful impact on the outcome of the yeast reduction. It is apparent that use of the sulfone moiety as a substituent to influence the efficiency and stereoselectivity in ketone reduction is substantially more effective than use of the analogous sulfide and sulfoxide moieties. | ||
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DOI_LINK | 10.1002/ejoc.201301729 | ||
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