Enhancement of Enantioselection in the Copper-Catalysed Intramolecular Buchner Reaction by Variation of the Counterion

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TY  - JOUR
  - O'Neill, S,O'Keeffe, S,Harrington, F,Maguire, AR
  - 2009
  - September
  - Synlett
  - Enhancement of Enantioselection in the Copper-Catalysed Intramolecular Buchner Reaction by Variation of the Counterion
  - Validated
  - ()
  - intramolecular Buchner reaction carbenes alpha-diazoketones copper bis(oxazoline) catalyst asymmetric catalysis ASYMMETRIC CYCLOPROPANATION H BONDS ALPHA-DIAZOKETONES INSERTION COMPLEXES CARBENOIDS SOLVENT REAGENT WATER
  - 2312
  - 2314
  - Variation of the enantioselection of the copper-catalysed intramolecular Buchner reaction of diazoketones with the nature of the counterion is reported significantly the presence of the non-coordinating BARF anion leads to enhanced enantioselectivities when the aryl group bears electron-withdrawing halo substituents.
  - DOI 10.1055/s-0029-1217709
DA  - 2009/09
ER  - 
@article{V43334774,
   = {O'Neill,  S and O'Keeffe,  S and Harrington,  F and Maguire,  AR },
   = {2009},
   = {September},
   = {Synlett},
   = {Enhancement of Enantioselection in the Copper-Catalysed Intramolecular Buchner Reaction by Variation of the Counterion},
   = {Validated},
   = {()},
   = {intramolecular Buchner reaction carbenes alpha-diazoketones copper bis(oxazoline) catalyst asymmetric catalysis ASYMMETRIC CYCLOPROPANATION H BONDS ALPHA-DIAZOKETONES INSERTION COMPLEXES CARBENOIDS SOLVENT REAGENT WATER},
  pages = {2312--2314},
   = {{Variation of the enantioselection of the copper-catalysed intramolecular Buchner reaction of diazoketones with the nature of the counterion is reported significantly the presence of the non-coordinating BARF anion leads to enhanced enantioselectivities when the aryl group bears electron-withdrawing halo substituents.}},
   = {DOI 10.1055/s-0029-1217709},
  source = {IRIS}
}
AUTHORSO'Neill, S,O'Keeffe, S,Harrington, F,Maguire, AR
YEAR2009
MONTHSeptember
JOURNAL_CODESynlett
TITLEEnhancement of Enantioselection in the Copper-Catalysed Intramolecular Buchner Reaction by Variation of the Counterion
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDintramolecular Buchner reaction carbenes alpha-diazoketones copper bis(oxazoline) catalyst asymmetric catalysis ASYMMETRIC CYCLOPROPANATION H BONDS ALPHA-DIAZOKETONES INSERTION COMPLEXES CARBENOIDS SOLVENT REAGENT WATER
VOLUME
ISSUE
START_PAGE2312
END_PAGE2314
ABSTRACTVariation of the enantioselection of the copper-catalysed intramolecular Buchner reaction of diazoketones with the nature of the counterion is reported significantly the presence of the non-coordinating BARF anion leads to enhanced enantioselectivities when the aryl group bears electron-withdrawing halo substituents.
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ISBN_ISSN
EDITION
URL
DOI_LINKDOI 10.1055/s-0029-1217709
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