IRIS publication 43334810
Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition
RIS format for Endnote and similar
TY - JOUR - O'Leary, P,Maguire, AR - 2009 - September - Arkivoc - Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition - Validated - () - Rhodium catalysis diazoketone Diels-Alder stereoselective azulenone DIAZOMETHYL KETONES BUCHNER REACTION CARBENOIDS PRODUCTS INSERTION - 130 - 151 - Rhodium catalysed intramolecular aromatic additions of diazoketones followed by Diels-Alder cycloadditions with carbon-based dienophiles leads in a highly stereoselective manner to polycyclic frameworks containing eight stereogenic centres completely controlled by the single stereocentre present in the diazoketone precursor. These cycloadditions provide interesting mechanistic insight into a dynamic equilibrium in methoxy-substituted azulenones. DA - 2009/09 ER -
BIBTeX format for JabRef and similar
@article{V43334810, = {O'Leary, P and Maguire, AR }, = {2009}, = {September}, = {Arkivoc}, = {Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition}, = {Validated}, = {()}, = {Rhodium catalysis diazoketone Diels-Alder stereoselective azulenone DIAZOMETHYL KETONES BUCHNER REACTION CARBENOIDS PRODUCTS INSERTION}, pages = {130--151}, = {{Rhodium catalysed intramolecular aromatic additions of diazoketones followed by Diels-Alder cycloadditions with carbon-based dienophiles leads in a highly stereoselective manner to polycyclic frameworks containing eight stereogenic centres completely controlled by the single stereocentre present in the diazoketone precursor. These cycloadditions provide interesting mechanistic insight into a dynamic equilibrium in methoxy-substituted azulenones.}}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | O'Leary, P,Maguire, AR | ||
YEAR | 2009 | ||
MONTH | September | ||
JOURNAL_CODE | Arkivoc | ||
TITLE | Efficient construction of novel carbocyclic frameworks via intramolecular aromatic addition of diazoketones followed by Diels-Alder cycloaddition | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | Rhodium catalysis diazoketone Diels-Alder stereoselective azulenone DIAZOMETHYL KETONES BUCHNER REACTION CARBENOIDS PRODUCTS INSERTION | ||
VOLUME | |||
ISSUE | |||
START_PAGE | 130 | ||
END_PAGE | 151 | ||
ABSTRACT | Rhodium catalysed intramolecular aromatic additions of diazoketones followed by Diels-Alder cycloadditions with carbon-based dienophiles leads in a highly stereoselective manner to polycyclic frameworks containing eight stereogenic centres completely controlled by the single stereocentre present in the diazoketone precursor. These cycloadditions provide interesting mechanistic insight into a dynamic equilibrium in methoxy-substituted azulenones. | ||
PUBLISHER_LOCATION | |||
ISBN_ISSN | |||
EDITION | |||
URL | |||
DOI_LINK | |||
FUNDING_BODY | |||
GRANT_DETAILS |