Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides

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TY  - JOUR
  - Kelly, P,Lawrence, SE,Maguire, AR
  - 2007
  - January
  - Synlett
  - Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides
  - Validated
  - ()
  - asymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE
  - 1501
  - 1506
  - Enantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed.
  - DOI 10.1055/s-2007-982555
DA  - 2007/01
ER  - 
@article{V43335909,
   = {Kelly,  P and Lawrence,  SE and Maguire,  AR },
   = {2007},
   = {January},
   = {Synlett},
   = {Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides},
   = {Validated},
   = {()},
   = {asymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE},
  pages = {1501--1506},
   = {{Enantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed.}},
   = {DOI 10.1055/s-2007-982555},
  source = {IRIS}
}
AUTHORSKelly, P,Lawrence, SE,Maguire, AR
YEAR2007
MONTHJanuary
JOURNAL_CODESynlett
TITLEChemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORDasymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE
VOLUME
ISSUE
START_PAGE1501
END_PAGE1506
ABSTRACTEnantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed.
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ISBN_ISSN
EDITION
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DOI_LINKDOI 10.1055/s-2007-982555
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