IRIS publication 43335909
Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides
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TY - JOUR - Kelly, P,Lawrence, SE,Maguire, AR - 2007 - January - Synlett - Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides - Validated - () - asymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE - 1501 - 1506 - Enantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed. - DOI 10.1055/s-2007-982555 DA - 2007/01 ER -
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@article{V43335909, = {Kelly, P and Lawrence, SE and Maguire, AR }, = {2007}, = {January}, = {Synlett}, = {Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides}, = {Validated}, = {()}, = {asymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE}, pages = {1501--1506}, = {{Enantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed.}}, = {DOI 10.1055/s-2007-982555}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Kelly, P,Lawrence, SE,Maguire, AR | ||
YEAR | 2007 | ||
MONTH | January | ||
JOURNAL_CODE | Synlett | ||
TITLE | Chemoselectivity and enantioselectivity in copper-catalysed oxidation of aryl benzyl sulfides | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
SEARCH_KEYWORD | asymmetric catalysis oxidation copper sulfoxides Schiff bases AQUEOUS HYDROGEN-PEROXIDE EFFICIENT ASYMMETRIC OXIDATION CHIRAL SCHIFF-BASES KINETIC RESOLUTION ORGANIC SULFIDES SULFOXIDES COMPLEXES ROUTE BIOTRANSFORMATION HYDROPEROXIDE | ||
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ISSUE | |||
START_PAGE | 1501 | ||
END_PAGE | 1506 | ||
ABSTRACT | Enantioselective copper-catalysed oxidation of aryl benzyl sulfides yields enantioenriched sulfoxides (up to 81% ee) in modest yield. This is the highest enantioselectivity reported using a copper catalyst in enantioselective sulfide oxidation. The enhancement of the enantioselectivity of this method through the use of additives is discussed. | ||
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DOI_LINK | DOI 10.1055/s-2007-982555 | ||
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