IRIS publication 43339888
Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems
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TY - JOUR - Maguire, AR,Buckley, NR,O'Leary, P,Ferguson, G - 1996 - November - Chemical Communications - Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems - Validated - () - 2595 - 2596 - Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case. DA - 1996/11 ER -
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@article{V43339888, = {Maguire, AR and Buckley, NR and O'Leary, P and Ferguson, G }, = {1996}, = {November}, = {Chemical Communications}, = {Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems}, = {Validated}, = {()}, pages = {2595--2596}, = {{Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case.}}, source = {IRIS} }
Data as stored in IRIS
AUTHORS | Maguire, AR,Buckley, NR,O'Leary, P,Ferguson, G | ||
YEAR | 1996 | ||
MONTH | November | ||
JOURNAL_CODE | Chemical Communications | ||
TITLE | Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems | ||
STATUS | Validated | ||
TIMES_CITED | () | ||
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START_PAGE | 2595 | ||
END_PAGE | 2596 | ||
ABSTRACT | Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case. | ||
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