Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems

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TY  - JOUR
  - Maguire, AR,Buckley, NR,O'Leary, P,Ferguson, G
  - 1996
  - November
  - Chemical Communications
  - Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems
  - Validated
  - ()
  - 2595
  - 2596
  - Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case.
DA  - 1996/11
ER  - 
@article{V43339888,
   = {Maguire,  AR and Buckley,  NR and O'Leary,  P and Ferguson,  G },
   = {1996},
   = {November},
   = {Chemical Communications},
   = {Excellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems},
   = {Validated},
   = {()},
  pages = {2595--2596},
   = {{Highly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case.}},
  source = {IRIS}
}
AUTHORSMaguire, AR,Buckley, NR,O'Leary, P,Ferguson, G
YEAR1996
MONTHNovember
JOURNAL_CODEChemical Communications
TITLEExcellent stereocontrol in intramolecular Buchner cyclisations and subsequent cycloadditions; Stereospecific construction of polycyclic systems
STATUSValidated
TIMES_CITED()
SEARCH_KEYWORD
VOLUME
ISSUE
START_PAGE2595
END_PAGE2596
ABSTRACTHighly diastereoselective rhodium(II) acetate-catalysed intramolecular addition of alpha-diazo ketones to aromatic rings to form the azulenones 3 has been achieved; the norcaradiene form of 3 undergoes efficient stereospecific cycloaddition with phenyltriazolinedione, in either a stepwise or a tandem process, leading to the pentacyclic systems 4 as a single diastereomer in each case.
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